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inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_fa7f034c9f68f02dea967e7065d31448
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publicationDate 2018-01-24-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber EP-3272760-A1
titleOfInvention 1,1 -bis (phosphino) ferrocene ligands for alkoxycarbonylation
abstract Compound according to formula (I)nin whichnR 2, R 4 are each independently selected from - (C 1 -C 12) -alkyl, - (C 3 -C 12) -cycloalkyl, - (C 3 -C 12) -heterocycloalkyl, - (C 6 -C 20) -aryl;neach of R 1, R 3 is a - (C 3 -C 20) heteroaryl radical;nR 1, R 3 are each independently selected with one or more substituents selected from - (C 1 -C 12) -alkyl, - (C 3 -C 12) -cycloalkyl, - (C 3 -C 12) -heterocycloalkyl, -O (C 1 -C 12) -alkyl, -O- (C 1 -C 12) -alkyl- (C 6 -C 20) -aryl, -O- (C 3 -C 12) -cycloalkyl, -S- (C 1 -C 12) -alkyl, -S- (C 3 -C 12) -cycloalkyl, -COO- (C 1 -C 12) -alkyl, -COO- (C 3 -C 12) -cycloalkyl, - CONH (C 1 -C 12) -alkyl, -CONH- (C 3 -C 12) -cycloalkyl, -CO- (C 1 -C 12) -alkyl, -CO- (C 3 -C 12) -cycloalkyl , -N - [(C 1 -C 12) -alkyl] 2, - (C 6 -C 20) -aryl, - (C 6 -C 20) -aryl (C 1 -C 12) -alkyl, (C 6 -C 20) aryl-O- (C 1 -C 12) -alkyl, - (C 3 -C 20) -heteroaryl, - (C 3 -C 20) -heteroaryl- (C 1 -C 12 ) Alkyl, - (C 3 -C 20) heteroaryl-O- (C 1 -C 12) alkyl, -COOH, -OH, -SO 3 H, -NH 2, halogen;nandnR 2, R 4, if they are - (C 1 -C 12) -alkyl, - (C 3 -C 12) -cycloalkyl, - (C 3 -C 12) -heterocycloalkyl or - (C 6 -C 20 ) -Aryl, each independently with one or more substituents selected from - (C 1 -C 12) alkyl, - (C 3 -C 12) cycloalkyl, - (C 3 -C 12) heterocycloalkyl, -O (C 1 -C 12) -alkyl, -O- (C 1 -C 12) -alkyl- (C 6 -C 20) -aryl, -O- (C 3 -C 12) -cycloalkyl, -S- (C 1 -C 12) -alkyl, -S- (C 3 -C 12) -cycloalkyl, -COO- (C 1 -C 12) -alkyl, -COO- (C 3 -C 12) -cycloalkyl, - CONH (C 1 -C 12) -alkyl, -CONH- (C 3 -C 12) -cycloalkyl, -CO- (C 1 -C 12) -alkyl, -CO- (C 3 -C 12) -cycloalkyl , -N - [(C 1 -C 12) -alkyl] 2, - (C 6 -C 20) -aryl, - (C 6 -C 20) -aryl (C 1 -C 12) -alkyl, (C 6 -C 20) aryl-O- (C 1 -C 12) -alkyl, - (C 3 -C 20) -heteroaryl, - (C 3 -C 20) -heteroaryl- (C 1 -C 12 ) Alkyl, - (C 3 -C 20) heteroaryl-O- (C 1 -C 12) alkyl, -COOH, -OH, -SO 3 H, -NH 2, halogen. The invention furthermore relates to Pd complexes of the compound according to the invention and to their use in an alkoxycarbonylation process.
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priorityDate 2016-07-19-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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