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inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_441f38725732a4f3f0b42bbdff894322
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publicationDate 2018-01-03-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber EP-3263547-A1
titleOfInvention Process for the production of di- and polyamines of the diphenylmethane series
abstract The invention relates to a production process for di- and polyamines of the diphenylmethane series by the rearrangement of a condensation product of aniline and a methylene group-supplying agent preferably selected from the group consisting of aqueous formaldehyde solution, gaseous formaldehyde, para-formaldehyde, trioxane and mixtures thereof, wherein said condensation product is reacted in the presence of at least one silica-alumina catalyst, said catalyst having n€¢ a surface area as determined by the BET method carried out according to ASTM D3663 - 03 (2015) of from 200 m 2 /g to 520 m 2 /g, preferably of from 350 m 2 /g to 495 m 2 /g, particularly preferably of from 400 m 2 /g to 490 m 2 /g, n€¢ a molar ratio of silica / alumina on the catalyst surface of A, n€¢ an overall ( bulk ) molar ratio of silica / alumina of C , and n€¢ a quotient B = A / C ; nsaid catalyst being characterised in that "low" A values (i.e. equal to or lower than 8.0) are combined with "high" B values (i.e. of from 1.50 to 3.00), and "high" A values (i.e. larger than 8.00, especially equal to or larger than 8.50) are combined with "low" B values (i.e. of from 0.15 to 1.40).
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