| Predicate |
Object |
| assignee |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_12a135a933620c99beab01d4ac785d25
http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_c85d78c6a4459b5dbbc49c82a4c5c107 |
| classificationCPCAdditional |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J2231-766
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J2531-66
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J2531-64
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C2531-22
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C2531-34 |
| classificationCPCInventive |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C5-373
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J31-2295
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C5-333 |
| classificationIPCInventive |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C5-373
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J31-02
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C5-333 |
| filingDate |
2016-01-08-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| inventor |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_572d2e9a617049d512497113d492478f
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_d713038ef10310daf1a18f8a99e665d2
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_b834e7017d3658300dd31f63e262dbb1
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_039746f0410ce2336154b4d7efd98443 |
| publicationDate |
2017-11-15-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationNumber |
EP-3242863-A1 |
| titleOfInvention |
Process for dehydrogenation of alkyl-containing compounds using molybdenum and tungsten nitrosyl complexes |
| abstract |
A process for the dehydrogenation of alkyl-containing compounds comprises reacting an alkyl-containing compound and a Group VI nitrosyl complex characterized as a transition metal complex having the composition Cp'M(NO)(R1)(R2), wherein Cp' is selected from certain substituted and unsubstituted η 5 -cyclopentadienyl groups; M is W or Mo; and R1 and R2 are independently selected from CH 2 C(CH 3 ) 3 ; CH 2 Si(CH 3 ) 3 ; CH 2 (C 6 H 5 ); CH 3 ; hydrogen; and η 3 -allyl; provided that if R1 is hydrogen, R2 is η 3 -allyl; under conditions such that the alkyl-containing compound is converted to an olefin, and in particular embodiments, a terminal olefin. The dehydrogenation can be carried out using a neat and/or undried alkyl-containing compound and/or may be conducted under air, and does not require a sacrificial olefin to drive the reaction, thereby increasing convenience and decreasing cost in comparison with some other dehydrogenation processes. |
| priorityDate |
2015-01-09-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| type |
http://data.epo.org/linked-data/def/patent/Publication |