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filingDate 2016-02-10-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_ecc1c8e0edee8a0733421d53a82b5271
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publicationDate 2017-08-16-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber EP-3205399-A1
titleOfInvention Method for grafting polysiloxanes on surfaces of photocatalytic metal oxides, polysiloxane-grafted metal oxide surfaces and applications thereof
abstract The present invention relates to a method for grafting polysiloxanes on surfaces of photocatalytic metal oxides by light illumination which comprises at least the following steps: na) providing a surface of a photocatalytically active metal oxide; nb) providing a polysiloxane or a mixture of polysiloxanes on the metal oxide surface; nc) irradiating the reaction mixture with light in a wavelength range from 180 nm to 550 nm for a sufficient time to generate reactive moieties in said polysiloxanes and to form covalent Si-O-Me (Me = metal) bonds between said reactive moieties of the polysiloxanes and the metal oxide surface; nd) optionally separating unreacted polysiloxane molecules from the polysiloxane-grafted metal oxide surface; nwherein no silane coupling agent or cross-linking agent needs to be present in the reaction mixture and/or participates in said grafting reaction. n A further aspect of the invention relates to the hydrophobic and photocatalytically active polysiloxane-grafted metal oxide surface obtainable by said method and to articles comprising said surface.
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