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publicationDate 2017-02-22-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber EP-3131934-A2
titleOfInvention Improved catalyst system for producing polyethylene copolymers in a high temperature solution polymerization process
abstract Catalyst system for producing ethylene copolymers in a high temperature solution process, the catalyst system comprising (i) a metallocene complex of formula (I) wherein M is Hf or Zr X is a sigma ligand, L is a bridge of the formula -SiR8 2-, wherein each R8 is independently a C1-C20-hydrocarbyl, tri(C1-C20-alkyl)silyl, C6-C20-aryl, C7-C20-arylalkyl or C7-C20-alkylaryl n is 0, 1 or 2 R1 and R1' are the same or can be different and can be a linear or branched C1-C6-alkyl group, R2 and R2' are the same or are different and are a CH2-R9 group, with R9 being H or linear or branched C1-C6-alkyl group R5 and R5' are the same or are different and can be H or a linear or branched C1-C6-alkyl group or a OR group, wherein R is a C1-C6-alkyl group R6 and R6' are the same or are different and can be H or a C(R10)3 group, with R10 being the same or different and R10 can be H or a linear or branched C1-C6-alkyl group or R5 and R6 and/or R5' and R6' taken together form an unsubstituted 4-7 membered ring condensed to the benzene ring of the indenyl moiety, with the proviso that if R5 and R6 as well as R5' and R6' taken together form an unsubstituted 5 membered ring condensed to the benzene ring of the indenyl moiety then R2 and R2' are not a C1-alkyl group; and R7 and R7' can be the same or are different and can be H or a linear or branched C1-C6-alkyl group (ii) an aluminoxane cocatalyst and (iii) optionally a boron containing cocatalyst
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