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inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_348b3bb716cbb5a2ad033604fe22119b
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publicationDate 2012-09-12-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber EP-2497588-A1
titleOfInvention Continuous flow process for the preparation of colloidal solutions of nanoparticles, colloidal solutions and uses thereof
abstract A continuous flow process for the preparation of a colloidal solution of Cu 2 A x SnSe y nanoparticles, wherein A is selected from Cd, Hg, Ni and Zn, 0‰¤x‰¤1, and 3‰¤y‰¤4, which comprises a) mixing in a continuous flow reaction unit under inert atmosphere and at an appropriate temperature, an appropriate amount of each of i) a solution of an A salt in an inert organic solvent; ii) a solution of a Sn salt in an inert organic solvent; iii) a solution of a Cu salt in an inert organic solvent; iv) a Se coordination compound; and, v) one or more stabilising agents selected from primary (C 12 -C 18 )-amine, a (C 12 -C 18 )-carboxylic acid, a (C 10 -C 14 )-phosphonic acid, and a mixture of any of the amines with any of the acids; the inert organic solvent is equal or different for each salt, has a dielectric constant <10, and a boiling temperature between 100-350°C; b) progressively heating the mixture up to a temperature between 100-350°C at a speed between 10 s-1 0 min; and, c) collecting the resulting Cu 2 A x SnSe y nanoparticle colloidal solution of step b). A colloidal solution of Cu 2 A x SnSe y nanoparticles with an average size between 1-100 nm, and a variance of the size distribution up to 20%, wherein A is selected from Cd, Hg and Ni, 0‰¤x‰¤1, and 3‰¤y‰¤4; and uses thereof. And methods for the manufacture of a photovoltaic cell, a photodetector or a thermoelectric device, comprising preparing the colloidal solution as defined above, and applying the colloidal solution onto an appropriate substrate
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