http://rdf.ncbi.nlm.nih.gov/pubchem/patent/EP-2376444-A1
Outgoing Links
Predicate | Object |
---|---|
assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_f5f38e7534f1f9389859c8a9ea58592e |
classificationCPCAdditional | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C2601-14 |
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C303-20 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C309-07 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C303-02 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C309-25 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C309-24 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C309-24 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C303-20 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D261-14 |
filingDate | 2009-12-11-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_4df75625efa5407f6f7cd6cf53024032 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_03efe46db1ba1203c5e31c11ca862ae3 |
publicationDate | 2011-10-19-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | EP-2376444-A1 |
titleOfInvention | A method for preparing sulfur-containing compounds |
abstract | The invention provides a method for preparing sulfur-containing compounds, the method comprising reacting a donor compound comprising at least one sulfur having at least one lone pair of electrons, with an acceptor compound; wherein the reaction occurs in the presence of an amine, optionally an amine catalyst, capable of activating the sulfur having at least one lone pair of electrons; and wherein the reaction occurs via the formation of an transient intermediate species, optionally a transient intermediate species, between the amine, optionally the amine catalyst and the donor compound; and wherein the donor compound is selected from the group consisting of a sulfurous acid, a sulfenic acid and a sulfinic acid or a salt, ester or amide of a sulfurous acid, a sulfenic acid and a sulfinic acid. The invention also provides sulfur-containing compounds of the formula: wherein R is selected from: (a) 1 -(4-Nitro-phenyl)-3-oxo-3-phenyl-propane; (b) 2-(3-Methyl-4-nitro-isoxazol-5-yl)-1 -phenyl-ethane; (c) 1-(4-Methoxy-phenyl)-2-(3-methyl-4-nitro-isoxazol-5-yl)-ethane; (d) 2-(3-Methyl-4-nitro-isoxazol-5-yl)-1-(4-nitro-phenyl)-ethane; (e) 1-(4-Fluoro-phenyl)-2-(3-methyl-4-nitro-isoxazol-5-yl)-ethane; (f) 1 -(4-Chloro-phenyl)-2-(3-methyl-4-nitro-isoxazol-5-yl)-ethane; and (g) 3-Oxo-cyclohexane. Finally, the invention provides use of chiral sulfur-containing compounds obtainable by the above-mentioned method or chiral sulfur-containing compounds as mentioned above for the resolution of racemic mixtures of amines. |
priorityDate | 2008-12-11-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
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