http://rdf.ncbi.nlm.nih.gov/pubchem/patent/EP-2297074-A1
Outgoing Links
Predicate | Object |
---|---|
assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_adb0e564374fedf34b36103d36e6455a |
classificationCPCAdditional | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07B2200-09 |
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C29-56 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C403-24 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C29-56 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C33-048 |
filingDate | 2009-06-02-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_cd67e072583e12575c8c53743478ff33 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_53ea5f48ff6353c5f1b794066f6c43cb |
publicationDate | 2011-03-23-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | EP-2297074-A1 |
titleOfInvention | Process for the rearrangement of allyl alcohols |
abstract | The present invention is directed to a process for isomerizing a pent-l-en-3-ol according to formula (1) to a mixture of the stereoisomers Z-pent-2-en-1-ol (2) and E-pent-2-en-1-ol (3) according to formulae (2) and (3) wherein R 1 is selected from alkyl, aryl, and alkylaryl radicals, R 2 is selected from H, alkyl, and aryl radicals; which process comprises reacting the pent-1-en-3-ol (1) in the presence of a heterogeneous acid catalyst either in water or in a multiphase solvent system. The heterogeneous acid catalyst is preferably selected from the group consisting of Brønsted acids on a carrier, strong acidic cation exchangers and polymers having acidic groups. The products of the process according to the present invention are important intermediates for the manufacture of isoprenoids such as vitamin A and derivatives thereof and carotenoids. |
isCitedBy | http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-10518049-B2 |
priorityDate | 2008-05-30-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 53.