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filingDate 2009-05-28-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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publicationDate 2011-02-02-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber EP-2279158-A2
titleOfInvention A process for dehydrochlorinating 1,1,1,2-tetrafluoro-2-chloropropane to 2,3,3,3-tetrafluoropropene in the presence of an alkali metal-doped magnesium oxyfluoride catalyst and methods for making the catalyst
abstract A process for making a fluorinated olefin. The process has the step of dehydrochlorinating a hydrochlorofluorocarbon having at least one hydrogen atom and at least one chlorine atom on adjacent carbon atoms in the presence of a catalytically effective amount of a catalyst composition. The catalyst composition is represented by the following: n wt.% MX/M'O y F z , wherein 0<y<1 and 0<z<2 and wherein y + z/2 = 1; M is an alkali metal ion selected from the group consisting of Li + , Na + , K + , Rb + , and Cs + ; X is a halogen ion selected from the group consisting of F - , Cl - , Br - , and I - , M' is a bivalent metal ion; wherein n is a weight percentage of about 0.05% to about 50% MX based on the total weight of the MX and M'O y F z , and wherein y and z are the mole fractions of oxygen and fluorine in M'O y F z , respectively. There are also methods for making catalyst compositions.
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