| abstract |
An oxynitride phosphor activated by a rare earth element, represented by the formula Me x Si 12-(m+n) Al (m+n) O n N 16-n :Re1 y Re2 x , wherein a part or all of metal Me (where Me is at least one metal selected from the group consisting of Ca, Mg, Y and lanthanide metals excluding La and Ce) in α-sialon solid solution, is substituted by lanthanide metal Re1 (where Re1 is at least one metal selected from the group consisting of Ce, Pr, Eu, Tb, Yb and Er), or two lanthanide metals Re1 and a coactivator Re2 (where Re2 is Dy), to be an emission center. n A sialon type phosphor in the form of a powder comprising at least 40 wt% of α-sialon represented by the formula (Ca x ,M y ) (Si,Al) 12 (O,N) 16 (where M is at least one metal selected from the group consisting of Eu, Tb, Yb and Er, 0.05<(x+y)<0.3, 0.02<x<0.27 and 0.03<y<0.3). and having a structure such that Ca sites of Ca-α-sialon are partially substituted by other metal M, at most 40 wt% of β-sialon, and at most 30 wt% of unreacted silicon nitride. |