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classificationCPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D209-46
classificationIPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D209-44
filingDate 2007-02-09-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2009-08-19-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_07ce1e0b4b80e35dff71e8ee4eba9db6
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_d03d386058a3d44e511461b95057a82e
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_1e7cdd009c25aa3f29c5e2a0edf09880
publicationDate 2009-08-19-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber EP-1984335-B1
titleOfInvention Improved process for the preparation of stable nitroxyl radicals
abstract Process for the preparation of stable nitroxyl radicals (I) starting from N-benzylphthalimide in two steps. In the first step, the intermediate N-benzyl-1, 1, 3, 3-tetra- alkylisoindoline is prepared by treatment with a Grignard reagent, prepared in methyl-tert-butyl ether, of N- benzylphthalimide, obtained in the same reaction environ - ment starting from phthalic anhydride and benzylamine. In the second step, the N-benzyl-1, 1, 3 , 3-tetra- alkylisoindoline is transformed into the nitroxyl radical by hydrogenolysis and subsequent oxidation with hydrogen peroxide in the presence of a catalyst selected from acids and salts of polymolybdic or polytungstic acids.
priorityDate 2006-02-16-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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