| Predicate |
Object |
| assignee |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_3c76ec809e6770d8a407b75885507948 |
| classificationCPCAdditional |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J2231-70 |
| classificationCPCInventive |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J31-006
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J31-0237
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J31-0239
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C45-294
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C45-38
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C45-29
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C45-30
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C45-82
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C45-39 |
| classificationIPCInventive |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C45-39
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C45-33
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C45-30
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C45-29
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C45-38
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C45-82 |
| filingDate |
2005-02-24-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| inventor |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_cd748e283a21e5c26f73552189583ce5
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_b919b3f014cb7c1770aa53024c8b71a3
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_3fa8250fcbc08d80d0cf276448452cfc
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_abb3a252e978168b606d81a567d1a910
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_7f15e4faa76ea902adecb900969184bf |
| publicationDate |
2006-11-08-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationNumber |
EP-1718590-A1 |
| titleOfInvention |
Catalyst system for aeorobic oxidation of primary and secondary alcohols. |
| abstract |
The present invention relates to a process of oxidation of alcohols selectively to aldehydes or ketones with molecular oxygen using a TEMPO based catalyst, Fe-bipyridyl or Fe-phenantroline co-catalyst and N- bromosuccinimide promoter in acetic acid solvent. The oxidation takes places at high rates and high aldehyde selectivity at temperatures in the range 45-50°C and oxygen or air pressures of 0-15psi. The alcohol conversion of 95-100% and aldehyde selectivity higher than 95% are achieved over 3-4 hours reaction time. Aldehydes such as 3,3-dimethyl-l-butanal can be produced efficiently using the present invention. |
| priorityDate |
2004-02-26-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| type |
http://data.epo.org/linked-data/def/patent/Publication |