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filingDate 2005-12-20-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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publicationDate 2006-07-12-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber EP-1679335-A2
titleOfInvention Siloxane block-copolymers
abstract A) Anlagerung von SiH-Gruppen enthaltenden Organopolysiloxanen an Vinylsiloxane in Gegenwart von Platin- oder Rhodiumkatalysatoren, mit der Maßgabe, dass die Organopolysiloxane im mindestens 6-fachen molaren Überschuss, bezogen auf das Vinylsiloxan, vorliegt und weiterer Umsetzung des Reaktionsproduktes in mindestens einer der Stufen B) Übergansmetall-katalysierter teilweiser oder vollständiger Addition der SiH-Gruppen an Alkenyl-und/oder Alkinylverbindungen, C) unter Mitverwendung eines Katalysators teilweiser oder vollständiger Umsetzung der nach obiger Reaktion(en) verbliebenen RSiH-Gruppen mit mindestens einem Alkohol, aus der Gruppe der linearen oder verzweigten, gesättigten, ein- oder mehrfach ungesättigten, aromatischen, aliphatisch-aromatischen, gegebenenfalls Halogenatome enthaltenden Monoalkohole, Polyethermonoalkohole, Polyestermonoalkohole, Aminoalkohole. The invention relates to organopolysiloxanes obtained by A) addition of SiH-containing organopolysiloxanes to vinylsiloxanes in the presence of platinum or rhodium catalysts, with the proviso that the organopolysiloxanes in at least 6-fold molar excess, based on the vinyl siloxane, is present and further reaction of the reaction product in at least one of the steps B) transition-metal catalyzed partial or complete addition of the SiH groups to alkenyl and / or alkynyl compounds, C) with the use of a catalyst partially or completely reaction of the above reaction (s) remaining RSiH groups with at least one alcohol, from the group of linear or branched, saturated, mono- or polyunsaturated, aromatic, aliphatic-aromatic, optionally halogen atoms containing monoalcohols, polyether monoalcohols, polyester mono alcohols, amino alcohols.
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