http://rdf.ncbi.nlm.nih.gov/pubchem/patent/EP-1578530-A4
Outgoing Links
Predicate | Object |
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assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_d155a7366c234993d31166b37a12351f |
classificationCPCAdditional | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08F110-02 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08F4-65925 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08F4-65908 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08F4-65916 |
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08F10-00 |
classificationIPCAdditional | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F110-02 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F4-659 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F4-6592 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F10-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F4-02 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F4-60 |
filingDate | 2003-10-21-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_54b166a012d81f47d895ec76f1217f67 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_7c0fb091c1ce5d279881ed655d310b33 |
publicationDate | 2006-07-05-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | EP-1578530-A4 |
titleOfInvention | BIMETALLIC CATALYSTS, THEIR POLYMERIZATION PROCESS AND BIMODAL POLYOLEFINS |
abstract | Bimetallic catalysts, and methods of producing a bimetallic catalyst comprising a modified Ziegler-Natta catalyst and a metallocene are provided, in one embodiment the method including combining: (a) a Ziegler-Natta cataylst comprising a Group 4, 5 or 6 metal halide and/or oxide, optionally including a magnesium compound, with (b) a modifier compound (“modifier”), wherein the modifier compound is a Group 13 alkyl compound, to form a modified Ziegler-Natta catalyst. Also provided is a method of olefin polymerization using the bimetallic catalyst of the invention. The modified Ziegler-Natta catalyst is preferably non-activated, that is, it is unreactive towards olefin polymerization alone. In one embodiment, the molar ratio of the Group 13 metal (of the modifier) to the Group 4, 5 or 6 metal halide and/or oxide is less than 10:1 in one embodiment. The bimetallic catalyst of the present invention are useful in producing bimodal polymers, particularly bimodal polyethylene, having a Polydispersity (Mw/Mn) of from 12 to 50. These bimodal polyolefins are useful in such articles as pipes and films. |
priorityDate | 2002-12-31-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 329.