http://rdf.ncbi.nlm.nih.gov/pubchem/patent/EP-1437373-A4

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filingDate 2002-09-18-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_6e9fc7cf3145dd502d75f8fdd1439c1e
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publicationDate 2004-12-01-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber EP-1437373-A4
titleOfInvention PROCESS FOR PRODUCING POLY RESIN (AROMATIC DICARBOXYL ETHYLENE-ESTER) AND PRODUCT FORMED THEREFROM
abstract Process for producing poly(ethylene-aromatic dicarboxylate ester) resin comprises subjecting a diester of an aromatic dicarboxylic acid and an ethylene glycol to condensation-polymerization in the presence of a catalyst comprising a mixture of titanium- and phosphorus- compounds. Process for producing poly(ethylene-aromatic dicarboxylate ester) resin comprises subjecting a diester of an aromatic dicarboxylic acid and an ethylene glycol to condensation-polymerization in the presence of a catalyst. The catalyst comprises a mixture of titanium- and phosphorus- compounds, and is obtained by regulating the concentration of P and Ti atoms of a reaction product of, or an unreacted mixture of, a P-containing compound component and a Ti-containing compound component. The titanium compound component contains one or more Ti-alkoxide compounds and a reaction product between a Ti-alkoxide and an aromatic polycarboxylic acid or its anhydride. The P-containing compound component contains at least one compound represented by general formula (1), (2) and (3). [Image] R 1>, R 2>, R 3>1-4C alkyl group; X : -CH 2- or group represented by (1a); R 4>2-18C alkyl or 6-20C aryl group; n : 1 or 2; p : 0 or 1 (when n = 1), and 0 (when n = 2); m, ma, mb : 0 or 1. The amount of the constituents of the catalyst satisfy the following relationships. 2 = M r i= 15 (a) 1 = (M p/ M r i) = 15 (b) 10 = (M r i+ M p) = 100 (c) M r iratio of the amount of Ti (mmol) contained in the catalyst to the total amount of mol of ethylene-aromatic dicarboxylate ester contained in the poly(ethylene-aromatic dicarboxylate ester); and M p : ratio of the amount of P (mmol) contained in the catalyst to the total amount of mol of ethylene-aromatic dicarboxylate ester contained in the poly(ethylene-aromatic dicarboxylate ester).
priorityDate 2001-09-20-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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Total number of triples: 42.