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publicationDate 2004-03-03-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber EP-1393801-A1
titleOfInvention Silver catalyst for the epoxidation of propylene
abstract (i) Silber, (ii) mindestens eine Erdalkalimetallverbindung, (iii) eine Kaliumverbindung oder ein Gemisch einer Kaliumverbindung mitnmindestens einer weiteren Verbindung, wobei das Gemisch einennSchmelzpunkt unterhalb 340 °C aufweist, und (iv) eine Kombination einer Cäsiumverbindung mit wenigstens einer Verbindungneines Elementes, ausgewählt aus der Gruppe Molybdän, Rheniumnund Wolfram, numfasst.Process for the preparation of propylene oxide by gas phase oxidation of a mixture comprising propylene and oxygen, at a temperature of 100 to 300 ° C and a pressure of 1 to 30 bar over a catalyst, characterized in that the catalyst (i) silver, (ii) at least one alkaline earth metal compound, (iii) a potassium compound or a mixture of a potassium compound with at least one further compound, the mixture having a melting point below 340 ° C., and (iv) a combination of a cesium compound with at least one compound of an element selected from the group consisting of molybdenum, rhenium and tungsten, includes.
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