http://rdf.ncbi.nlm.nih.gov/pubchem/patent/EP-1328597-A1
Outgoing Links
Predicate | Object |
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assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_ef85d661b9a18307a5a59ff4eca96233 |
classificationCPCAdditional | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/Y10T428-31504 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/Y10T428-31855 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/Y10T428-31935 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/Y10T428-31928 |
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08F4-52 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C09J4-00 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F220-18 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F4-52 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C09J4-02 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C09J4-00 |
filingDate | 2001-10-23-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_27e1c6bb4708034a52f1c788ff2488aa http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_e5de3f64876bbf7d8edd6dc88e612709 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_65e934316a034290f258e894cf8cc2c4 |
publicationDate | 2003-07-23-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | EP-1328597-A1 |
titleOfInvention | Quaternary boron compound polymerisation initiators, polymerisable compositions and uses thereof for bonding low surface energy substrates |
abstract | Metal alkyl borohydrides are used as initiators of polymerisation, particularly in adhesive compositions for bonding a wide range of substrates including low surface energy substrates such as polyolefins. As described, the metal alkyl borohydrides are of the formula I <CHEM> wherein R<1> is C1 - C10 alkyl, R<2>, R<3> and R<4>, which may be the same or different, are H, D, C1 - C10 alkyl or C1 - C10 cycloalkyl, phenyl, or phenyl-substituted C1 - C10 alkyl or C1 - C10 cycloalkyl, provided that any two of R<1> - R<4> may optionally be part of a carbocyclic ring, and M+ is a metal ion. In particular, alkali metal trialkyl borohydrides are used, the alkali metal salt being selected from the group consisting of: Lithium triethylborohydride, Sodium triethylborohydride, Potassium triethylborohydride, Lithium tri-sec-butylborohydride, Sodium tri-sec-butylborohydride, Potassium tri-sec-butylborohydride, Lithium 9-borabicyclo Ä3.3.1Ü-nonane (9BBN) hydride, Lithium thexylborohydride, Lithium trisiamylborohydride, Potassium trisiamylborohydride and Lithium triethylborodeuteride. A polymerisable composition, particularly a two part adhesive composition. comprises: a) a free-radically polymerisable monomer component, and b) an effective amount of an initiator system for initiating polymerisation of the free-radically polymerisable monomer, said initiator system comprising a metal alkyl borohydride. |
priorityDate | 2000-10-23-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
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