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grantDate 2004-12-08-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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publicationDate 2004-12-08-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber EP-1316545-B1
titleOfInvention Biphasic ammoximation
abstract Preparation of an oxime comprises ammoxidation of a ketone or an aldehyde in a system of one aqueous phase and one inert hydrocarbon phase in the presence of a catalyst system comprising (i) a heterogeneous catalyst based on titanium, silicon and oxygen and (ii) an ammonium salt. An interphase contactor is present. Preparation of an oxime comprises reacting a ketone or an aldehyde with hydrogen peroxide and ammonia in a system of one aqueous phase and one phase consisting of a hydrocarbon inert under the reaction conditions, in the presence of a catalyst system comprising at least two components. The first component is present in heterogeneous form and is based on titanium, silicon and oxygen. The second component is a homogeneously dissolved or suspended ammonium salt. At least one interphase contactor is also present.
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