http://rdf.ncbi.nlm.nih.gov/pubchem/patent/EP-1310172-A1
Outgoing Links
Predicate | Object |
---|---|
assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_0efa077d881a96aeb1e29b21ef1bbb58 |
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01D3-141 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C51-10 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C51-44 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/A23K20-105 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C53-06 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01D3-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C51-10 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C53-04 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/A23K20-105 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C51-42 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07B61-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C51-44 |
filingDate | 2002-11-07-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_dc9ecd6bb065fc909ad4d5dbde2d73ed http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_ce024da1a101b7c630503fe5aa40bfda http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_ca5814c259f2ed5e758aa5c85afbca28 |
publicationDate | 2003-05-14-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | EP-1310172-A1 |
titleOfInvention | Process for the preparation of metalformate-formic acid mixtures |
abstract | a) Umsetzung von mindestens einem Metallhydroxid mit Kohlenmonoxid oderneinem Kohlenmonoxid-haltigen Gas in Gegenwart eines Katalysators in einernwasserhaltigen Lösung zu dem oder den entsprechenden Metallformiat(en); b) destillative Abtrennung des Wassers und des Katalysators; c) Zumischen von Ameisensäure; d) gegebenenfalls Einstellen der Temperatur der nach den Schritten a) bis c)nerhaltenen Metallformiat-Ameisensäure-Mischung auf Lagertemperatur; nwobei in Schritt a) als Metallhydroxide die Hydroxide von Alkalimetallen und/oder Erdalkalimetallenneingesetzt werden und Schritt c) auch zeitlich vor Schritt b) durchgeführtnwerden kann.The invention relates to a process for the preparation of metal formate-formic acid mixtures comprising the following steps: a) reaction of at least one metal hydroxide with carbon monoxide or a carbon monoxide-containing gas in the presence of a catalyst in a water-containing solution to the corresponding metal formate (s); b) separation of the water and the catalyst by distillation; c) admixing formic acid; d) optionally adjusting the temperature of the metal formate-formic acid mixture obtained after steps a) to c) to storage temperature; wherein in step a) the hydroxides of alkali metals and / or alkaline earth metals are used as metal hydroxides and step c) can also be carried out before step b).n n n At least one catalyst from the group consisting of alcohol and formic acid ester is used as the catalyst. Preferred catalysts are linear C 1 -C 4 -, branched C 3 -C 4 alkanols and their formic acid esters. Preferred metal hydroxides are the hydroxides of sodium, potassium and / or calcium. The concentration of the formic acid used in step c) is generally 80 to 99.99% by weight in water, and the storage temperature in step d) is a temperature of 0 to 40 ° C. |
isCitedBy | http://rdf.ncbi.nlm.nih.gov/pubchem/patent/WO-2005044771-A2 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/WO-2005044771-A3 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-103951558-A |
priorityDate | 2001-11-09-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 66.