Predicate |
Object |
assignee |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_1fa893ad762099de57d3c9c93b13d968 |
classificationCPCAdditional |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J2531-825 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J2231-543 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J2231-325 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C2531-22 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J2231-4211 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J2531-821 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J2231-4233 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J2231-4261 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J2231-546 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J2231-4266 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J2231-321 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J2231-323 |
classificationCPCInventive |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07F7-0829 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07B37-04 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07F15-0033 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07F15-0046 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07F11-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J31-2273 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J31-2265 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C6-04 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07F7-0896 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07F15-0073 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07F15-002 |
classificationIPCInventive |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07F17-02 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07B61-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J31-18 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07F15-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07F11-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J31-22 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07F7-08 |
filingDate |
2002-09-23-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
grantDate |
2005-12-28-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_202e250dac2b76bdcd1e531cbb1f2f63 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_9d263636db76e4f6128bc4fda4da0680 |
publicationDate |
2005-12-28-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber |
EP-1300410-B1 |
titleOfInvention |
Transition metal complexes comprising a diaminocarben ligand and their use in transition metal catalysed reactions |
abstract |
Transition metal complexes with diaminocarbene ligands are new. <??>Compounds of formula (I) are new. <??>M = Sub-Group 6-8 metal; <??>R<1>-R<4> = H or linear, branched or cyclic hydrocarbyl selected from 1-50C alkyl, 2-50C alkenyl or alkynyl, or 6-30C aryl (all optionally substituted with functional group(s)); <??>L = Neutral 2-electron donor ligands and/or part of a cyclic system and/or anionic ligands; <??>n = Integer. <??>R<1> and R<2> and/or R<3> and R<4> may form part of a ring system with 2-20 C atoms and one N atom (not including the carbons in the R groups; optionally with at least one ring H replaced by a functional group and/or with at least one ring C replaced by S, P, O or N), and/or R<1> and/or R<2> and/or R<3> and/or R<4> may be linked with one of the ligands L by a bridging group with 1-20 C atoms (not including those in the R groups). <??>Independent claims are also included for: <??>(1) Method for the production of (I) by preparation of a carbene ligand of formula (Ia) by deprotonation of a formamidinium salt with strong base or by the ammonia method, followed by a ligand-exchange reaction between (II) and suitable transition metal complexes; and <??>(2) Methods for the production of (I) by reacting compounds of formula (Ib) with transition metal complexes (salt metathesis), or by reacting these compounds with alkali metal alcoholates and then subjecting the resulting alcoholate adduct to ligand exchange with a transition metal complex. |
priorityDate |
2001-10-02-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type |
http://data.epo.org/linked-data/def/patent/Publication |