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filingDate 2000-06-15-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2004-09-01-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_74bfe4ac97730033a38a4d2f795049f8
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_51ffd5aee956421c6426bc8c5b722eee
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publicationDate 2004-09-01-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber EP-1192117-B1
titleOfInvention (e8,z10)-tetradeca-8,10-dienal, the method of its preparation and its use as sexual attractant for leafminer moths
abstract The subject of the invention are isomerically pure tetradeca-8,10-dienals, the synthetic preparation thereof and their use as sex attractants for leafminers of the genus Gracillariidae (Lepidotpera, Insecta), in particular the means of preparation of the (<i>E</i>8,<i>Z</i>10)-tetradeca-8,10-dienal and its utilization as a sex attractant for horse chestnut leafminer [<i>Cameraria ohridella</i> Deschka et Dimić 1985 (Lepidoptera:Gracillariidae)]. The title compound can be prepared so that (<i>E</i>)-9-(<i>tert</i>-butoxy)-1-jodnon-1-ene reacts with 1-pentyne in a basic solvent, preferably an alkylamine, in the presence of a Pd(0) catalyst mixed with a cuprous salt providing (<i>E)</i>)-14-(<i>tert</i>-butoxy)tetradec-6-en-4-yne, whereupon the above prepared enyne is reduced to provide (4<i>Z</i>,6<i>E</i>)-14-(<i>tert</i>-butoxy)tetradeca-4,6-diene, then a protection group is removed in an acidic environment and the prepared (8<i>E</i>,10<i>Z</i>)-tetradeca-8,10-dien-1-ol is further oxidized to give the (<i>E</i>8,<i>Z</i>10)-tetradeca-8,10-dienal. This compound is directly, in a solution or in a mixture with additional compounds, or in the form of its pro-pheromone derivatives, applied on an appropriate support and then used in diverse types of traps containing, beside the attractant, a moth restraint to control populations of the horse chestnut leafminer, or in mass-trapping devices for the moth males or in devices containing, beside the attractant, insecticides, a biocontrol agent, or compounds regulating insect development (IGR-Insect Growth Regulators), in which the attracted males are killed, or agents spread into leafminer populations, or, finally, the title compound can be dispersed into the atmosphere in concentrations capable of confusing the males and thus preventing their copulation with conspecific females.
isCitedBy http://rdf.ncbi.nlm.nih.gov/pubchem/patent/DE-102005056795-A1
priorityDate 1999-06-16-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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