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publicationDate 2001-08-01-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber EP-1120158-A1
titleOfInvention Catalytic systems of the Ziegler-Natta type
abstract a) eine Feststoffkomponente, enthaltend eine Verbindung des Titansnoder des Vanadiums, eine Verbindung des Magnesiums, einnteilchenförmiges anorganisches Oxid als Träger und eine internenElektronendonorverbindung,nsowie als Cokatalysator b) eine Aluminiumverbindung und c) gegebenenfalls eine weitere, externe Elektronendonorverbindung, nwobei das verwendete teilchenförmige, anorganische Oxid eine spezifischenOberfläche von 350 bis 1000 m 2 /g und einen mittlerennTeilchendurchmesser D im Bereich von 5 bis 60 µm aufweist und ausnTeilchen besteht, die sich aus Primärpartikeln mit einemnmittleren Teilchendurchmesser d im Bereich von 1 bis 10 µm zusammensetzennund die zwischen den Primärpartikeln Hohlräume oder Kanälenenthalten, wobei der makroskopische Anteil der Hohlräumenoder Kanäle mit einem Durchmesser größer 1 µm an den Teilchen dernanorganischen Oxide im Bereich von 5 bis 30 Vol.-% liegt und wobeindas molare Verhältnis zwischen der Verbindung des Magnesiumsnund dem teilchenförmigen, anorganischen Oxid 0,5:1 bis 2,0:1 beträgt.Catalyst systems of the Ziegler-Natta type, containing active ingredients a) a solid component containing a compound of titanium or vanadium, a compound of magnesium, a particulate inorganic oxide as a carrier and an internal electron donor compound, and as a cocatalyst b) an aluminum compound and c) optionally a further external electron donor compound, wherein the particulate inorganic oxide used has a specific surface area of 350 to 1000 m 2 / g and an average particle diameter D has in the range of 5 to 60 microns and consists of particles consisting of primary particles with an average particle diameter d in the range of 1 to 10 µm and which contain cavities or channels between the primary particles, the macroscopic proportion of the cavities or channels with a diameter greater than 1 µm in the particles of the inorganic oxides being in the range of 5 to 30% by volume and wherein the molar ratio between the compound of magnesium and the particulate inorganic oxide is 0.5: 1 to 2.0: 1.
priorityDate 2000-01-21-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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