Predicate |
Object |
assignee |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_b7b1787fdafc9a84f27a9e2e702132f8 |
classificationCPCAdditional |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J2531-13 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J2531-11 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J2531-46 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J2531-10 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J2531-0216 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08G63-83 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J21-063 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08G63-87 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08G63-84 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J23-18 |
classificationCPCInventive |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J31-04 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08G63-85 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J31-38 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J31-22 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08G63-82 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J31-26 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07F7-28 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J31-2239 |
classificationIPCAdditional |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08G63-87 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08G63-83 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08G63-84 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J21-06 |
classificationIPCInventive |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08G63-85 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08G63-82 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07F7-28 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J31-26 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J31-22 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J31-04 |
filingDate |
2001-01-08-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_09d9e84eba5af1eff6c11153933a42fb http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_def49e2bece6f4be9bb02622fd71beea |
publicationDate |
2001-07-11-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber |
EP-1114838-A1 |
titleOfInvention |
Polyester polycondensation with titanyl oxalate catalyst and a catalyst enhancer |
abstract |
The present invention is based upon the discovery that nontitanyl oxalates can enhance thencatalytic functionality of titanyl oxalate catalysts. This invention provides anovel catalyticncomposition containing a titanyl oxalate catalyst and a metallic oxalate catalyst enhancernand optionally containing a metallic cocatalyst such as an antimony based catalyst, Ansynergistic relationship has been discovered between titanyl oxalate catalyst and the catalystnenhancer. A synergistic relationship has also been discovered between the titanyl oxalatencatalyst, catalyst enhancer and a metallic cocatalyst such as antimony oxide or antimonyntriacetate. Also provided is an improved process of producing polyester by thenpolycondensation of polyester forming reactants in the presence of a catalytically effectivenamount of a polycondensation catalyst, wherein the improvement comprises utilizing, as thenpolycondensation catalyst, the novel catalyst composition containing a titanyl oxalate suchnas lithium titanyl oxalate and a catalyst enhancer such as a nontitanyl metallic oxalate likenlithium oxalate and optionally containing a metallic catalyst such as antimony oxide ornantimony triacetate. The improved process produces an improved polyester having lowernacetaldehyde numbers and good color. The titanyl oxalate/catalyst enhancer compositionncan be used as a polycondensation catalyst in combination with other catalysts to achievensynergistic catalytic activity. Preferred is a combination of lithium titanyl oxalate,nLi 2 TiO(C 2 O 4 ) 2 , lithium oxalate, Li 2 (C 2 O 4 ) 2 with antimony oxide or antimony triacetate ornantimony trisglycoxide. |
isCitedBy |
http://rdf.ncbi.nlm.nih.gov/pubchem/patent/WO-03072633-A1 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-7300998-B2 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/EP-1339492-A4 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/EP-1270641-A2 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/EP-1339492-A2 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/EP-1270641-A3 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/EP-1475402-A1 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/EP-1475402-A4 |
priorityDate |
2000-01-07-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type |
http://data.epo.org/linked-data/def/patent/Publication |