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filingDate 2000-12-08-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_ca6bad0edb084fe9e8128584d3c30055
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publicationDate 2001-06-27-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber EP-1111450-A1
titleOfInvention Core/shell emulsions with enhanced photographic response
abstract A silver halide photographic element comprises at least one silvernhalide emulsion layer comprising a silver halide emulsion comprising core/shellnsilver halide grains wherein the core region comprises silver bromide with fromnabout 5 to about 20% silver iodide and the shell region comprises silver bromidenwith about 0.1 to about 10% silver iodide and said layer contains a fragmentablenelectron donor compound of the formula X-Y' or a compound which contains anmoiety of the formula -X-Y'; nwherein n   X is an electron donor moiety, Y' is a leaving proton H or anleaving group Y, with the proviso that if Y' is a proton, a base, β - , isncovalently linked directly or indirectly to X, and wherein:n 1) X-Y' has an oxidation potential between 0 and about 1.4 V; and 2) the oxidized form of X-Y' undergoes a bond cleavage reaction to giventhe radical X • and the leaving fragment Y'; n   and, optionally,n 3) the radical X • has an oxidation potential ≤-0.7V.
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priorityDate 1999-12-20-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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