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filingDate 2000-04-07-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_6196555a688c4570f6fc27ecd5dbb3df
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publicationDate 2000-10-25-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber EP-1046639-A1
titleOfInvention Process for the preparation of pyrroles
abstract c) Palladium auf einem Oxid einer Seltenen Erde oder einem Oxid einesnElements der 4. Gruppe (IV. Nebengruppe) des Periodensystems oder d) eines Platin/Palladium-Gemischs auf Aluminiumoxid, einem Oxidneiner Seltenen Erde oder einem Oxid eines Elements der 4. Gruppe. nund 0 bis 70 Gew.-% Alkali- oder Erdalkalimetalloxid.There is a process for the preparation of pyrroles of general formula I. wherein R 1 , R 2 , R 3 and R 4 are identical or different and denote hydrogen atoms, alkyl groups with 1 to 12 carbon atoms or cycloalkyl groups with 3 to 12 carbon atoms, by dehydrating pyrrolidines of the general formula II wherein R 1 , R 2 , R 3 and R 4 have the meanings given above, in the presence of a supported noble metal catalyst. The dehydrogenation is carried out at temperatures in the range from 150 to 300 ° C. and pressures from 0.01 to 50 bar and the noble metal catalyst contains 30 to 100% by weight. c) palladium on an oxide of a rare earth or an oxide of an element of the 4th group (IV. subgroup) of the periodic table or d) a platinum / palladium mixture on aluminum oxide, a rare earth oxide or an oxide of an element of the 4th group. and 0 to 70% by weight of alkali or alkaline earth metal oxide.
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