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filingDate 2000-04-05-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_886d13795a9f66ef7e09222fd3b666bb
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publicationDate 2000-10-18-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber EP-1044951-A2
titleOfInvention Process for preparation of ethers in a catalytic distillation column
abstract A process for preparing ethers includes the steps of:nproviding a feedstock containing iso-olefins selected fromnthe group consisting of C5 iso-olefins, C6 iso-olefins andnmixtures thereof; mixing the feedstock with alkyl alcohol sonas to provide a reaction feedstock, feeding the reactionnfeedstock to a reactor zone in the presence of a firstnetherification catalyst whereby the alkyl alcohol reactsnwith the iso-olefins to form alkyl-tert-alkyl ethers so asnto provide an intermediate feedstock containing the ethersnand unreacted iso-olefins and alkyl alcohol; feeding thenintermediate feedstock to a catalytic distillation columnnhaving a second etherification catalyst defining a catalyticnzone; mixing additional alkyl alcohol to the intermediatenfeedstock so as to form azeotropes of the alkyl alcohol withnthe unreacted iso-olefins without forming azeotropes of thenalkyl alcohol with the ethers whereby the catalytic zone isnsubstantially free of the ethers and the unreacted iso-olefinsnreact with said alkyl alcohol in the catalytic zonento form additional alkyl-tert-alkyl ethers.
priorityDate 1999-04-06-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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