http://rdf.ncbi.nlm.nih.gov/pubchem/patent/EP-0934244-A1

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http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J23-644
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http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C45-38
filingDate 1997-10-13-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_1b5cde7c288d42a47b2205d2b40146e7
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_9c57e86796318575767b06176fd41676
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_e6b5f70f98b37987751605c008b2c825
publicationDate 1999-08-11-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber EP-0934244-A1
titleOfInvention Method for selective preparation of a 2-hydroxybenzoic acid and a 4-hydroxybenzaldehyde and derivatives
abstract The present invention concerns a process for the preparation of a 2-hydroxybenzoic acid and of a 4-hydroxybenzaldehyde and derivatives thereof from a mixture of two phenolic compounds, one carrying a formyl or hydroxymethyl group in the 2 position, and the other carrying a formyl or hydroxymethyl group in the 4 position. The invention also concerns the preparation of a 4-hydroxybenzaldehyde from said mixture. The invention more particularly concerns the preparation of 3-methoxy-4-hydroxybenzaldehyde and of 3-ethoxy4-hydroxybenzaldehyde, respectively known as "vanillin" and ethylvanillin". The process for the preparation of a 2-hydroxybenzoic acid and a 4-hydroxybenzaldehyde and derivatives thereof is characterised in that the formyl or hydroxymethyl group in the 2 position of compound (A) in a mixture of phenolic compounds, one (A) carrying a formyl or hydroxymethyl group in the 2 position, and the other (B) carrying a formyl or hydroxymethyl group in the 4 position, is selectively oxidised to a carboxy group and optionally a hydroxymethyl group of compound (B) in the 4 position is selectively oxidised to a formyl group, thus producing a mixture of a 2-hydroxybenzoic acid and a 4-hydroxybenzaldehyde.
priorityDate 1996-10-14-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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