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publicationDate 2001-03-07-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber EP-0903356-A4
titleOfInvention CRYSTALLINE POLYPROPYLENE, PREPARATION PROCESS, POLYPROPYLENE COMPOSITION AND THERMOFORMED ARTICLE
abstract A crystalline polypropylene which meets the following property requirements (1 to 4), contains a component insoluble in decane at 64 °C, is excellent particularly in hardness and rigidity, and has high melt tension and excellent moldability; a process for preparing the same; and a polypropylene composition and a thermoformed article comprising the above crystalline polypropylene: (1) an intrinsic viscosity [θ] (in decaline at 135 °C) of 0.5 to 10 dl/g; (2) a molecular weight distribution (Mz/Mw) of at least 5 as determined by gel permeation chromatography (GPC; o-chlorobenzene solvent, measurement temp. 140 °C); (3) a pendat isotacticity (mmmm fraction), an index of stereotacticity, of at least 98 % as determined by 13C-NMR spectroscopy; and (4) a D value of at least 4.0 as determined by the equation (I) based on loss tan δ¿0.05? and loss tan δ10 as measured at a temperature of 230 °C under constant strain by means of a melt viscoelasticity measuring instrument at frequencies of 0.05 rad/sec and 10 rad/sec. The number-average molecular weight of the component insoluble in decane at 64 °C is at most 25000.
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