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filingDate 1997-04-04-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_fdb06f48882bb1f374ada7dd910b0d56
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_064b06e65424538d6ad49c0cfcd189e5
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_0ebca6b786b785ede8673a662b34bc6f
publicationDate 1999-01-27-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber EP-0892771-A1
titleOfInvention Process for the manufacture of halogenated propanes containing end-carbon fluorine
abstract A process is disclosed for producing a compound of the formula: CF3CHXCF3-zYz where X and Y are independently selected from the group consisting of H and Cl, and z is 0 or 1. The process involves (1) contacting CCl3CHXCC3-zYz,CCl2-zYz=CXCC3, and/or CCl2CX=CC3-zYz starting material, with hydrogen fluoride at a temperature of less than 200 °C to produce a fluorination product of said starting material which includes at least 90 mole percent total of C3HXYzCl6-z-xFx saturated compounds and C3XYzCl5-z-yFy olefinic compounds, wherein x is an integer from 1 to 6-z and y is an integer from 1 to 5-z, (the fluorination product including no more than about 40 mole percent of the desired product, CF3CHXCF3-zYz); (2) contacting saturated compounds and olefinic compounds produced in (1) with hydrogen fluoride in the vapor phase at a temperature of from 200 °C to about 400 °C in the presence of a fluorination catalyst; and (3) reacting a sufficient amount of said compounds, wherein x is an integer from 1 to 5-z and olefinic compounds produced in (1) with hydrogen fluoride in the vapor phase at a temperature of from 200 °C to about 400 °C in the presence of a vapor phase fluorination catalyst to provide an overall selectivity to CF3CHXCF3-zYz of at least about 90 percent based upon the amount of starting material reacted with HF in (1) and (2).
priorityDate 1996-04-10-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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