http://rdf.ncbi.nlm.nih.gov/pubchem/patent/EP-0839783-A1

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filingDate 1997-10-24-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_ee1d26078735a26d0b9dbd72852ed56d
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publicationDate 1998-05-06-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber EP-0839783-A1
titleOfInvention Gas phase alkylation-liquid phase transalkylation process
abstract An alkylation/transalkylation process involving vapor phase alkylation of a benzenenfeedstock in a multi-stage alkylation zone having a plurality of series connected catalyst bedsncontaining a pentasil aromatic alkylation catalyst, such as silicalite, coupled with intermediatenseparation and recirculation steps and liquid phase transalkylation over a transalkylation catalystncomprising a molecular sieve having a pore size greater than the pore size of the silicalite. Thenbenzene containing feedstock is supplied to the multi-stage alkylation reaction zone along withna C 2 -C 4 alkylating agent operated under temperature and pressure conditions to maintain thenbenzene in the gas phase. Alkylated product is recovered from the alkylation zone and suppliednto a benzene recovery zone for the separation of the benzene from the alkylation product.nBenzene from the benzene recovery zone is recycled to the reaction zone. A higher boilingnbottom fraction containing a mixture of monoalkylated and polyalkylated aromatic componentsnis supplied to a secondary separation zone from which a monoalkylated aromatic component,n e.g. ethylbenzene, is recovered overhead with a heavier polyalkylated aromatic recovered as anbottom fraction. The bottom fraction may be applied to a tertiary separation zone.
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