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filingDate 1995-02-11-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_5017b4cb57fa5d9ad593f17bebf75a86
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publicationDate 1995-08-23-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber EP-0668329-A2
titleOfInvention Brilliant pigments with multiple coatings
abstract A) einer ersten, im wesentlichen aus Siliciumoxid, Siliciumoxidhydrat, Aluminiumoxid und/oder Aluminiumoxidhydrat bestehenden Schicht, B) einer zweiten, im wesentlichen aus Metall und/oder nichtselektiv absorbierendem Metalloxid bestehenden Schicht und C) gewünschtenfalls einer dritten, im wesentlichen aus farblosem oder selektiv absorbierendem Metalloxid bestehenden Schicht, erhältlich durchn a) naßchemische Belegung der Substratteilchen mit Siliciumoxid, Siliciumoxidhydrat, Aluminiumoxid und/oder Aluminiumoxidhydrat durch hydrolytische Zersetzung von organischen Silicium- und/oder Aluminiumverbindungen, bei denen die organischen Reste über Sauerstoffatome an die Metalle gebunden sind, in Gegenwart eines organischen Lösungsmittels, in welchem die Metallverbindungen löslich sind, und gegebenenfalls anschließende Trocknung, b) weitere Belegung der in Schritt a) erhaltenen Teilchen mit Metall durchn b1) Gasphasenzersetzung flüchtiger Metallverbindungen in einer inerten Atmosphäre oder b2) stromlose, naßchemische Metallabscheidung und gegebenenfalls anschließende Trocknung oder mit nichtselektiv absorbierendem Metalloxid durchn b3) Gasphasenzersetzung flüchtiger Metallverbindungen in Gegenwart von Sauerstoff und/oder Wasserdampf und c) gewünschtenfalls zusätzliche Belegung der in Schritt b) erhaltenen Teilchen mit farblosem oder selektiv absorbierendem Metalloxid durchn c1) Gasphasenzersetzung flüchtiger Metallverbindungen in Gegenwart von Sauerstoff und/oder Wasserdampf oder c2) naßchemische Belegung durch hydrolytische Zersetzung organischer Metallverbindungen, bei denen die organischen Reste über Sauerstoffatome an die Metalle gebunden sind, in Gegenwart eines organischen Lösungsmittels, in welchem die Metallverbindungen löslich sind, und anschließende Trocknung. Gloss pigments based on multi-coated platelet-shaped metallic substrates A) a first layer consisting essentially of silicon oxide, silicon oxide hydrate, aluminum oxide and / or aluminum oxide hydrate, B) a second layer consisting essentially of metal and / or non-selectively absorbing metal oxide and C) if desired, a third layer consisting essentially of colorless or selectively absorbing metal oxide, available through a) Wet chemical coating of the substrate particles with silicon oxide, silicon oxide hydrate, aluminum oxide and / or aluminum oxide hydrate by hydrolytic decomposition of organic silicon and / or aluminum compounds in which the organic radicals are bonded to the metals via oxygen atoms, in the presence of an organic solvent in which the Metal compounds are soluble, and optionally subsequent drying, b) further coating of the particles obtained in step a) with metal b1) gas phase decomposition of volatile metal compounds in an inert atmosphere or b2) Electroless, wet chemical metal deposition and optionally subsequent drying or with non-selectively absorbing metal oxide b3) gas phase decomposition of volatile metal compounds in the presence of oxygen and / or water vapor and c) if desired, additional coating of the particles obtained in step b) with colorless or selectively absorbing metal oxide c1) gas phase decomposition of volatile metal compounds in the presence of oxygen and / or water vapor or c2) Wet chemical coating by hydrolytic decomposition of organic metal compounds in which the organic radicals are bonded to the metals via oxygen atoms, in the presence of an organic solvent in which the metal compounds are soluble, and subsequent drying.
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