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filingDate 1995-01-16-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_349ec61e13cce1df720344604a7f4239
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_b76e186d40ce9e7dd8c7d6bd8b933247
publicationDate 1995-08-02-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber EP-0665255-A2
titleOfInvention N-Methylol derivates of polycondensates based on ureas and polyamines
abstract A) basischen Harnstoffen der Formel n n        HN(R 1 )-CO-N(R 2 )-X 1 -N(R 3 , R 4 )     (I), n n B) Polyaminen der Formel n n        (R 6 ,R 7 )N-X 2 -N(R 8 ,R 9 )     (II) n nund C) bifunktionellen Alkylierungsmitteln, wie zB. 1-Brom-3-Chlorpropan oder Epichlorhydrin, worinn X 1 C 2 -C 4 -Alkylen, X 2 C 2 -C 6 -Alkylen bedeutet, das durch -O-,NR 10 -, wobei R 10 für Wasserstoff oder C 1 C 4 -Alkyl steht, oder durch -NH-CO-NH- unterbrochen sein kann, R 1 und R 2 unabhängig voneinander Wasserstoff oder C- 1 -C 4 -Alkyl darstellen oder R 1 und R 2 gemeinsam Ethylen-1,2 oder Trimethylen bedeuten und R 3 und R 4 unabhängig voneinander Wasserstoff, C 1 -C 4 -Alkyl oder C 2 -C 4 -Hydroxyalkyl darstellen, wobei weiterhin R 3 den Rest -X 1 -N(R 2 )-CO-NHR 1 bedeuten kann und wobei R 3 und R 4 gemeinsam einen der Reste -CH 2 CH 2 -O-CH 2 CH 2 - oder-CH 2 CH 2 -N(R 5 )-CH 2 CH 2 - bedeuten können, worin R 5 Wasserstoff, C 1 -C 4 -Alkyl, C 2 -C 4 -Hydroxyalkyl, den Rest -X 1 -N(R 2 )-CO-NHR 1 oder den Rest -CO.NH 2 bedeutet, und R 6 , R 7 , R 8 und R 9 unabhängig voneinander für wasserstoff, C 1 -C 4 - Alkyl oder C 2 -C 4 -Aminoalkyl stehen und R 6 und R 7 gemeinsam und unabhängig hiervon R 8 und R 9 gemeinsam oder R 6 und R 8 gemeinsam und unabhängig hiervon R 7 und R 9 gemeinsam Ethylen-1,2 oder Trimethylen bedeuten können. N-methylol derivatives of polycondensates with quaternary N atoms A) basic ureas of the formula HN (R 1 ) -CO-N (R 2 ) -X 1 -N (R 3 , R 4 ) (I), B) Polyamines of the formula (R 6 , R 7 ) NX 2 -N (R 8 , R 9 ) (II) and C) bifunctional alkylating agents, such as. 1-bromo-3-chloropropane or epichlorohydrin, wherein X 1 C 2 -C 4 alkylene, X 2 C 2 -C 6 alkylene which can be interrupted by -O-, NR 10 -, where R 10 is hydrogen or C 1 C 4 -alkyl, or by -NH-CO-NH-, R 1 and R 2 independently represent hydrogen or C 1 -C 4 alkyl or R 1 and R 2 together represent ethylene-1,2 or trimethylene and R 3 and R 4 independently of one another represent hydrogen, C 1 -C 4 -alkyl or C 2 -C 4 -hydroxyalkyl, where R 3 can furthermore denote the radical -X 1 -N (R 2 ) -CO-NHR 1 and where R 3 and R 4 a 2 CH 2 -O-CH 2 CH 2 in common of the radicals -CH - or-CH 2 CH 2 -N (R 5) -CH 2 CH 2 - can, wherein R 5 is hydrogen, C 1 -C 4 alkyl , C 2 -C 4 -hydroxyalkyl, the radical -X 1 -N (R 2 ) -CO-NHR 1 or the radical -CO.NH 2 , and R 6 , R 7 , R 8 and R 9 independently of one another are hydrogen, C 1 -C 4 alkyl or C 2 -C 4 aminoalkyl and R 6 and R 7 together and independently thereof R 8 and R 9 together or R 6 and R 8 together and independently thereof R 7 and R 9 together Ethylene-1,2 or trimethylene can mean. n n n They are prepared by reacting the polycondensate with formaldehyde or a reagent that provides formaldehyde.n n n They are used as wet fast improvers for dyeings on cellulose and cellulose blended fabrics.
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