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filingDate 1993-09-03-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_3430c794bf68bfe6f5b9e11d8abb65c6
publicationDate 1995-06-21-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber EP-0658174-A1
titleOfInvention METHOD FOR PRODUCING POLYTETRAMETHYLENETHERGLYCOL DIESTERS WITH AN ALUMINOSILICATE CATALYST.
abstract An improved process for the preparation of polytetramethylene ether glycol diesters of the formula R-CO-O(CH2-CH2-CH2-CH2-O)n-COR1, in which R and R1 are identical or different and are an alkyl radical or a derivative thereof, by polymerization of tetrahydrofuran in the presence of a fixed-bed polymerization catalyst and in the presence of a carboxylic anhydride. The use of a catalyst selected from amorphous aluminium silicate, acid-activated and calcined kaolin or zeolite instead of the known natural montmorillonite catalysts having a cryptocrystalline three-layer structure means that polymers having more uniform properties and a narrower molecular weight distribution are now accessible at a higher polymerization rate.
priorityDate 1992-09-04-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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