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filingDate 1994-03-11-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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publicationDate 1994-09-28-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber EP-0617103-A1
titleOfInvention Aqueous dispersion of a polyurethane and a condensation resin
abstract (a) organischen Polyisocyanaten (b) Dihydroxylverbindungen mit einem Molekulargewicht über 500 bis 5000 g/mol, welche keine Ionengruppen oder in ionische Gruppen überführbaren Gruppen enthalten (c) Verbindungen mit mindestens eines gegenüber Isocyanat reaktiven funktionellen Gruppe und mindestens einer ionischen oder in eine ionische Gruppe überführbaren Gruppe, (d) gegebenenfalls von (c) verschiedenen Verbindungen mit mindestens zwei gegenüber Isocyanat reaktiven funktionellen Gruppen und einem Molgewicht von 60 bis 500 g/mol und das Polyurethan, oder dessen Prepolymer in einem mit Wasser mischbaren Lösungsmittel hergestellt und nach Zusatz des die Haftung verbessernden Polymeren in Wasser dispergiert wird und im Falle des Prepolymeren anschließend die weitere Umsetzung zum Polyurethan erfolgt, dadurch gekennzeichnet, daß es sich bei den die Haftung verbessernden Polymer um ein Kondensationsprodukt einer Verbindung (I), ausgewählt aus aromatischen Verbindungen mit einem aromatischen Ring, zwei kondensierten aromatischen Ringen der zwei durch eine C₁-C₈-Alkylengruppe verbundenen aromatischen Ringen, welche an mindestens einen Ring durch mindestens eine Hydroxygruppe und an den aromatischen Ringen gegebenenfalls durch 1 bis 3 C₁- bis C₁₂-Alkyl- oder -Alkoxygruppen substituiert sind, oder Gemischen dieser Verbindungen mit einer Verbindung (II), ausgewählt aus Verbindungen mit 2 bis 20 Kohlenstoffatomen und mindestens einer Keto- oder Aldehydgruppe, einem C₄- bis C₁₆-Diolefin, Verbindungen mit 2 bis 10 Kohlenstoffatomen und mindestens einer Dreifachbindung, deren Gemische oder deren Gemische mit Formaldehyd, wobei maximal 70 Mol-% der Verbindung (II) Formaldehyd sind, handelt.Aqueous dispersions containing a polyurethane and 5 to 60% by weight, based on the polyurethane, of a polymer which improves adhesion, the polyurethane being essentially composed of (a) Organic polyisocyanates (b) Dihydroxyl compounds with a molecular weight above 500 to 5000 g / mol, which contain no ion groups or groups which can be converted into ionic groups (c) compounds with at least one isocyanate-reactive functional group and at least one ionic group or one which can be converted into an ionic group, (d) optionally different from (c) compounds with at least two isocyanate-reactive functional groups and a molecular weight of 60 to 500 g / mol and the polyurethane, or its prepolymer, is prepared in a water-miscible solvent and, after the addition of the adhesion-improving polymer, is dispersed in water and, in the case of the prepolymer, further conversion to the polyurethane then takes place, characterized in that it improves the adhesion-improving properties Polymer around a condensation product of a compound (I) selected from aromatic compounds with an aromatic ring, two condensed aromatic rings of the two aromatic rings connected by a C₁-C₈-alkylene group, which are attached to at least one ring by at least one hydroxyl group and to the aromatic rings optionally substituted by 1 to 3 C₁ to C₁₂ alkyl or alkoxy groups, or mixtures of these compounds with a compound (II) selected from compounds having 2 to 20 carbon atoms and at least one keto or aldehyde group, a C₄ to C₁₆ -Diolefin, connections with 2 to 10 carbon atoms and at least one triple bond, their mixtures or their mixtures with formaldehyde, with a maximum of 70 mol% of the compound (II) being formaldehyde.
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