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filingDate 1992-07-10-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_056bacf024d0296ce326b228d7fa8256
publicationDate 1994-05-25-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber EP-0597961-A1
titleOfInvention Process using borane derived catalysts for preparation of syndiotactic vinyl aromatic polymers
abstract Process for the preparation of syndiotactic vinyl aromatic polymers comprising contacting at least one vinyl aromatic monomer which can be polymerized under polymerization conditions with a catalyst comprising a compound corresponding to the formula: LmMXn + RA, in which: L represents a delocalized pi linking group containing up to 50 non-hydrogen atoms; m is 0 or 1; M represents a metal from group 4 of the Periodic Table; X represents, in all cases, an anionic inert ligand containing up to 20 non-hydrogen atoms; n is an integer greater than or equal to 1 and the sum of m and n is 1 less than the valence of M; RA represents RB (C6F5) 3, where R represents hydride, hydrocarbyl, silyl, one of their combinations or one of their substituted derivatives having up to 20 non-hydrogen atoms. The invention also describes a process for preparing the catalyst.
priorityDate 1991-08-05-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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