abstract |
Potassium tetrafluoroaluminate and potassium hexafluoroaluminate have been produced by three new processes: (a) by reacting alumina trihydrate with freshly produced, hot, solvated potassium fluoride solution in presence of stoichiometric amounts and/or an excess of hydrogen fluoride, or (b) by reacting aluminum trifluoride trihydrate with hot aqueous solution of potassium fluoride or potassium bifluoride, or (c) by generating in situ potassium aluminate by reacting alumina trihydrate with hot aqueous potassium hydroxide and treating the same with aqueous or anhydrous hydrogen fluoride. |