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filingDate 1993-08-31-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_8378ac8c5805a22a098dd90c8c404001
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publicationDate 1994-03-16-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber EP-0587018-A2
titleOfInvention Thermoplastic moulding composition
abstract A: 3 bis 97 Gew.-% eines gegebenenfalls schlagzäh modifizierten thermoplastischen Harzes A aus, bezogen auf A,n A1: 50 bis 100 Gew.-% einer Hartphase A1 mit einer Viskositätszahl (VZ) von 50 bis 100 ml/g aus, bezogen auf A1n A11: 5 bis 90 Gew.-% eines Copolymeren A11 aus, bezogen auf A11,n A111: 50 bis 95 Gew.-% Styrol oder eines kernsubstituierten Styrolderivats (A111), A112: 5 bis 50 Gew.-% Acrylnitril (A112) undn A12: 10 bis 95 Gew.-% eines Copolymeren A12 mit einer VZ von 50 bis 70 ml/g aus, bezogen auf A12,n A121: 50 bis 95 Gew.-% α-Methylstyrol (A121) A122: 5 bis 50 Gew.-% Acrylnitril (A122) und A2: bis 50 Gew.-% eines teilchenförmigen Pfropfcopolymerisates aus, bezogen auf A2n A21: 15 bis 85 Gew.-% mindestens eines elastomeren Polymerisats A21 mit einer mittleren Teilchengröße von 30 bis 1000 nm auf der Grundlage eines ggf. in Form eines Copolymerisats vorliegenden 1,3-Polydiens oder eines vorzugsweise vernetzten kautschukelastischen Polyalkylacrylats (A211) als Pfropfgrundlage, und A22: 15 bis 85 Gew.-% einer auf das elastomere Polymerisat A21 aufgepfropften Hülle A22 aus, bezogen auf A22,n A221: 50 bis 90 Gew.-% mindestens eines vinylaromatischen Monomeren A221 und A222: 10 bis 50 Gew.-% mindestens eines polaren copolymerisierbaren ethylenisch ungesättigten Monomeren A222; und B: 3 bis 97 Gew.-% eines mindestens 70 % Einheiten der allgemeinen Formel I aufweisenden Polymethacrylimids (Polyglutarimids) Bn in der bedeutenn R¹ und R² unabhängig voneinander Wasserstoff, C₁-C₄-Alkyl oder C₆-C₁₈-Aryl und R³ Wasserstoff, C₁-C₈-Alkyl, C₅-C₁₂-Cycloalkyl oder C₆-C₁₈-Aryl. Thermoplastic molding composition based on a polymethacrylimide-modified ABS or ASA resin, essentially containing, based on the sum of A and B, A: 3 to 97% by weight of an optionally impact-modified thermoplastic resin A, based on A, A1: 50 to 100% by weight of a hard phase A1 with a viscosity number (VZ) of 50 to 100 ml / g, based on A1 A11: 5 to 90% by weight of a copolymer of A11, based on A11, A111: 50 to 95% by weight of styrene or a core-substituted styrene derivative (A111), A112: 5 to 50% by weight acrylonitrile (A112) and A12: 10 to 95% by weight of a copolymer A12 with a VZ of 50 to 70 ml / g, based on A12, A121: 50 to 95% by weight of α-methylstyrene (A121) A122: 5 to 50% by weight acrylonitrile (A122) and A2: up to 50% by weight of a particulate graft copolymer, based on A2 A21: 15 to 85% by weight of at least one elastomeric polymer A21 with an average particle size of 30 to 1000 nm on the basis of a 1,3-polydiene which may be in the form of a copolymer or a preferably crosslinked rubber-elastic polyalkyl acrylate (A211) as the graft base , and A22: 15 to 85% by weight of a shell A22 grafted onto the elastomeric polymer A21, based on A22, A221: 50 to 90% by weight of at least one vinylaromatic monomer A221 and A222: 10 to 50% by weight of at least one polar copolymerizable ethylenically unsaturated monomer A222; and B: 3 to 97% by weight of a polymethacrylimide (polyglutarimide) containing at least 70% of units of the general formula I B in the mean R1 and R2 independently of one another hydrogen, C₁-C₄-alkyl or C₆-C₁₈-aryl and R³ Hydrogen, C₁-C₈ alkyl, C₅-C₁₂ cycloalkyl or C₆-C₁₈ aryl.
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