http://rdf.ncbi.nlm.nih.gov/pubchem/patent/EP-0527221-A4

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filingDate 1992-03-03-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 1993-09-15-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber EP-0527221-A4
titleOfInvention Process for preparing polyolefins having a bimodal molecular weight distribution
abstract A two-step polymerization process for producing a polyolefin having a bimodal molecular weight distribution is provided. In step one, under polymerization conditions, at least two different alpha-olefins are contacted with a catalyst system which comprises an aluminoxane and a metallocene, selected from the group consisting of mono, di, and tri-cyclopentadienyls and substituted cyclopentadienyls, of a metal selected from titanium, vanadium, chromium, zirconium, niobium, molybdenum, hafnium, tantalum, and tungsten, provided however if said metal is titanium then a metallocene of at least one other of said metals is present such that a first polymerization mixture is formed which comprises a low crystallinity, high molecular weight, copolymer, unreacted monomer, unreacted comonomer, and catalyst. This is followed by contacting, under polymerization conditions, hydrogen (and optionally additional alpha-olefin), with said first polymerization mixture which comprises copolymer, unreacted monomer, unreacted comonomer, and catalyst, such that a second polymerization mixture is formed which comprises a low crystallinity, high molecular weight copolymer, and a high crystallinity, low molecular weight homopolymer.
priorityDate 1991-03-04-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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