http://rdf.ncbi.nlm.nih.gov/pubchem/patent/EP-0467732-A1
Outgoing Links
Predicate | Object |
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assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_481648b910607c5dcbe4ba1c7a2b84a8 |
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08G61-10 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C25B3-29 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C25B3-29 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08G61-10 |
filingDate | 1991-06-25-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_9e4f766114826ef12cb135130d72adc8 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_8903300ce1a58479acf18f8d5297a244 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_2b10406574ef982dc244385a6d740fb3 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_d96b62c26349b7edbd1cdc49b1c27eba http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_b873ad408f389dc73809cadb3214fe9f |
publicationDate | 1992-01-22-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | EP-0467732-A1 |
titleOfInvention | Process for synthesizing sublimable linear phenylene based oligomers of controlled length |
abstract | 1- l'électrolyse du catalyseur et sa réaction avec l'un des deux oligomères à un premier potentiel, 2- la réduction de l'espèce d'insertion obtenue selon l'étape 1, et sa réaction avec le second oligomère à un second potentiel inférieur au premier potentiel, et 3- la récupération de l'oligomère sublimable ainsi obtenu, les deux oligomères inférieurs utilisés étant des oligomères mono- ou dihalogénés, identiques ou différents. the present invention relates to a process for the preparation of phenyl-based sublimable oligomers, linear and of controlled length, by electrochemical coupling of two lower oligomers within a monocompartmented cell with three electrodes, in the presence of an organometallic catalyst , characterized in that it comprises: 1- the electrolysis of the catalyst and its reaction with one of the two oligomers at a first potential, 2- the reduction of the insertion species obtained according to step 1, and its reaction with the second oligomer at a second potential lower than the first potential, and 3- recovery of the sublimable oligomer thus obtained, the two lower oligomers used being mono- or dihalogenated oligomers, identical or different. n n n the present invention also relates to the sublimable phenylene-based oligomers obtained according to this process, and their applications in electronics and / or optics. |
priorityDate | 1990-06-27-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 73.