http://rdf.ncbi.nlm.nih.gov/pubchem/patent/EP-0418013-A2
Outgoing Links
| Predicate | Object |
|---|---|
| assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_d43c883aa035c2b0560e1968520554fd |
| classificationCPCAdditional | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C2601-04 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C2601-02 |
| classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C231-12 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07F3-02 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07F3-003 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C51-15 |
| classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C51-15 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C231-12 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07F3-02 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07F3-00 |
| filingDate | 1990-09-10-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_4831df1f7c19a5ffbfe0f7194d51ab72 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_850ce0f0d379112c40ef4d3d8e22e59c http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_f60b3871a2d0d642c19104e8f08c4a11 |
| publicationDate | 1991-03-20-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationNumber | EP-0418013-A2 |
| titleOfInvention | Direct magnesiation of organic materials |
| abstract | A method for magnesiating a compound substituted with one or more activating groups beta (ortho) to a carbon atom having a hydrogen substituent to be deprotonated. The compound is either a saturated cyclic compound in which the carbon-carbon bonds are strained greater than the carbon-carbon bonds of cyclobutane, or an unsaturated compound in which the carbon atom to be deprotonated is located no more than one position away from a pi-bonded carbon atom. The method contacts the substituted compound with a reactant having the formula:n wherein W is:n and R₁, R₂, R₃ and R₄ independently include hydrogen, alkyl, aryl, alkylaryl, and heteroaryl, or R and R₂ and/or R₃ and R₄ together form a cyclic residue. Compounds substituted with one or more magnesium-containing groups and one or more activating groups are also disclosed. The activated compounds are either saturated cyclic compounds having carbon-carbon bonds that are strained greater than the carbon-carbon bonds of cyclobutane, or unsaturated compounds. The one or more magnesium-containing groups have the structure:n with R₁ and R₂ independently including hydrogen, alkyl, aryl, alkylaryl, and heteroaryl, or R₁ and R₂ together forming a cyclic residue. A method by which such compounds are reacted with electrophilic reagents replacing the magnesium containing groups with substituent groups is also disclosed. |
| isCitedBy | http://rdf.ncbi.nlm.nih.gov/pubchem/patent/WO-2021204667-A1 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/WO-2021204666-A1 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/JP-2007501770-A http://rdf.ncbi.nlm.nih.gov/pubchem/patent/WO-2004048389-A1 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/WO-2005014560-A1 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-7385062-B2 |
| priorityDate | 1989-09-11-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
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