http://rdf.ncbi.nlm.nih.gov/pubchem/patent/EP-0391212-A3

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filingDate 1990-03-27-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 1991-12-11-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber EP-0391212-A3
titleOfInvention Process for preparing bifunctional z-stilbene compounds, new bifunctional z-stilbene compounds and their use for preparing polymers
abstract Bifunctional stilbene compounds of the formula containing at least one Z-configured stilbene group are made by using compounds of formula with an acetylene of the formula HC≡C-R⁴ (III), in the presence of a palladium catalyst and a base at temperatures of 30 to 160 ° C, the obtained compounds in the presence of a base in compounds of the formula transferred, then the compounds of formula (IV) with compounds of formula in the presence of a palladium catalyst and a base at temperatures of 30 to 160 ° C, then the acetylene compounds obtained in the presence of catalysts with hydrogen or with other reducing agents to Z-stilbene compounds of the formula reduced and the functional groups D and D¹ in the above-mentioned functional groups Z and Y of formula (I) converted in a known manner or the Z-stilbene compounds of the formula (VI) in the case that D and D¹ are at least one bromine atom with compounds of the formula H₂C = CHR⁷ (VII), in the presence of a palladium catalyst and a base at temperatures of 30 to 160 ° C and the functional groups D, D¹ and D² in the functional groups Z and Y of formula (I) leads in the usual manner or the compounds of the formula (IV) with compounds of the formula in the presence of a palladium catalyst and a base at temperatures of 30 to 160 ° C, then the acetylene compounds obtained are reduced in the presence of catalysts with hydrogen or with other reducing agents to corresponding Z-stilbene compounds and then the functional groups D into the functional groups Z and Y of formula (I) transferred in known manner.
priorityDate 1989-04-07-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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Total number of triples: 38.