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filingDate 1990-03-22-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_4d6cbffa07d3cfb76e5e144e01a0e534
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_f64e71effebd82c1b25043dc6cf0e14f
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http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_92f486fae91a3f568ec564c5519008b6
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publicationDate 1990-10-03-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber EP-0389962-A2
titleOfInvention Sinterable ceramic powder and method of making it, silicon nitride ceramic made therefrom, method of making it and its use
abstract A) dadurch erhältlich ist, daß man mindestens eines der Oligosilazane der Formel (I)n worin a, b, c, d die Molfraktionen der jeweiligen Struktureinheiten bedeuten und wobei 0≦a≦1, 0≦b≦1, 0≦c<0°7, 0≦d<0.7, 0.3≦a+b, c+d<0.7 und n etwa 2 bis etwa 12 ist, mit mindestens einem der Chlorsilane R⁶R⁷SiCl₂, R⁸SiCl₃, Cl₂R⁹Si-CH₂CH₂-SiR⁹Cl₂, Cl₃Si-CH₂CH₂-SiR¹⁰Cl₂ bei 30 bis 300°C umsetzt, wobei unabhängig voneinander R¹, R², R⁴, R⁶, R⁷, R⁸ = H, C₁-C₆-Alkyl oder C₂-C₆-Alkenyl und R³, R⁵, R⁹, R¹⁰ = C₁-C₆-Alkyl oder C₂-C₆-Alkenyl ist, oder B) folgende Formel hatn worin R und R* gleich oder verschieden sein können und R, R* = C₁-C₄-Alkyl, Vinyl oder Phenyl und R¹ = C₁-C₄-Alkyl ist und x, y die Molfraktionen der beiden Struktureinheiten bedeuten, wobei x + y = 1 und x = 0,7-0,95 ist. The invention relates to a new sinterable ceramic powder, its production, its further processing to silicon nitride ceramic, and this material itself and its use. The sinterable ceramic powder is produced by melting a polysilazane or dissolving it in an organic solvent, suspending a powdered sintering aid in this melt or solution, then pyrolyzing the melt or the residue obtained after evaporation of the solvent in a protective gas atmosphere at 500 to 1600 ° C., whereby the polysilazane either A) can be obtained by at least one of the oligosilazanes of the formula (I) where a, b, c, d are the mole fractions of the respective structural units and where 0 ≦ a ≦ 1.0, ≦ b ≦ 1.0, ≦ c <0 ° 7, 0 ≦ d <0.7, 0.3 ≦ a + b, c + d <0.7 and n is about 2 to about 12, with at least one of the chlorosilanes R⁶R⁷SiCl₂, R⁸SiCl₃, Cl₂R⁹Si-CH₂CH₂-SiR⁹Cl₂, Cl₃Si-CH₂CH₂-SiR¹⁰Cl₂ at 30 to 300 ° C, independently of one another R¹, R², R⁴, R⁶ , R⁷, R⁸ = H, C₁-C₆-alkyl or C₂-C₆-alkenyl and R³, R⁵, R⁹, R¹⁰ = C₁-C₆-alkyl or C₂-C₆-alkenyl, or B) has the following formula wherein R and R * may be the same or different and R, R * = C₁-C₄-alkyl, vinyl or phenyl and R¹ = C₁-C₄-alkyl and x, y are the mole fractions of the two structural units, where x + y = 1 and x = 0.7-0.95. n n n A molded body can be formed from the ceramic powder obtained in this way and then produced by sintering silicon nitride ceramic. However, it is also possible to form a shaped body from the solidified melt or the unpyrolyzed residue obtained after evaporation of the solvent and then pyrolyze and sinter it.n n n Components for strong mechanical, thermal and corrosive stress can be produced from the ceramic obtained.
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http://rdf.ncbi.nlm.nih.gov/pubchem/patent/EP-0560258-A3
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http://rdf.ncbi.nlm.nih.gov/pubchem/patent/EP-0493802-A1
http://rdf.ncbi.nlm.nih.gov/pubchem/patent/EP-0698447-A3
http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-5649984-A
http://rdf.ncbi.nlm.nih.gov/pubchem/patent/EP-0698447-A2
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