http://rdf.ncbi.nlm.nih.gov/pubchem/patent/EP-0379081-A3

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classificationIPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D303-14
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http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07F7-18
filingDate 1990-01-12-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 1991-04-03-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber EP-0379081-A3
titleOfInvention Process for the preparation of 1-hydroxymethyl oxiranes z-substituted in position 2
abstract Process for the preparation of 1-hydroxy-methyl-oxiranes of the general formula I and ent-I which are Z-substituted in the 2-position, in which the substituents A, B independently of one another C₁-C₄-alkyl, phenyl, naphthyl, diphenyl or phenyl substituted by one to three radicals from the group halogen, C₁-C₄-alkyl, C₁-C₄-alkoxy, C₁-C₄-haloalkyl, nitro or phenoxy mean by ketones of the general formula II in which A and B have the meanings given above and X represents a group which can be eliminated under the reaction conditions, is reacted with trimethyl sulfonium methyl sulfate and a suitable base or with dimethyloxosulfonium methylide, and new ketones of the general formula II ' in which the substituents A ′ phenyl or 4-fluorophenyl, B ′ 2-fluorophenyl, 2-chlorophenyl, 2-bromophenyl or 2-trifluoromethylphenyl and X ′ hydroxy or a leaving group mean, with the proviso that B 'is not 2-chlorophenyl when A' is phenyl.
priorityDate 1989-01-18-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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Total number of triples: 29.