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filingDate 1989-11-08-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_31412a8318cd629e30f8d4de93fd1cbc
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publicationDate 1990-05-16-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber EP-0368631-A2
titleOfInvention A process for the homo- or copolymerization of alpha-olefin, and a catalyst system used in the process
abstract The polymerization of alpha-olefins in a gas phase involves the problem of agglomeration of the product into particles disadvantageous from the viewpoint of its handl­ing. In the present invention this problem has been solved by means of a new type of process for the homo- or copoly­merization of alpha-olefins. In the process the catalyst system is pretreated by contacting and reacting a transi­tion-metal compound which is solid or on a solid carrier with an organoaluminum compound, and possibly an electron donor, in a liquid medium, and by drying the thus formed reaction product to produce a solid catalyst system. The thus pretreated solid and active catalyst system is then fed together with an alpha-olefin in the gaseous state into a gas-phase reactor, and polymerization is carried out by contacting them with each other. By feeding a dry and ac­tive catalyst system into the gas-phase reactor, it is possible to avoid the agglomeration of the product which occurs in conventional processes in which an organoaluminum compound and possibly an electron donor are fed in a liquid medium into the reactor.
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priorityDate 1988-11-08-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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