abstract |
Butyl rubber having olefinic unsaturation of about 0.2 to about 2.5 mole percent halogenated to contain chlorine bound to the polymer of about 0.05 to about 0.39 weight percent or bromine of about 0.05 to about 0.49 weight percent. The new halogenated butyl rubber when cured with heat reactive phenolic resin cure system, typically including a metal oxide such as zinc oxide, has improved performance properties including tension set, hot elongation, resistance to scorch and improved stress-strain properties and flex fatigue resistance after aging. Such advantages are particularly evident when the halogenated polymer is used in compositions useful as curing elements such as those used in the manufacture of pneumatic tires. |