http://rdf.ncbi.nlm.nih.gov/pubchem/patent/EP-0314165-A1
Outgoing Links
Predicate | Object |
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assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_9e5302e08e56037ff7bc5c9b6fcc29f9 |
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08F10-02 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F4-62 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F4-60 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F110-02 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F10-02 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F10-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F4-638 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F4-68 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F4-658 |
filingDate | 1988-10-28-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_9f04864be1a3f609bb35754e37834905 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_898fa14a8a99c045dd0b10d771488e9b |
publicationDate | 1989-05-03-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | EP-0314165-A1 |
titleOfInvention | Process for the production of polyethylene with a broad and/or bimodal molecular weight distribution |
abstract | A process for the production of an ethylene homopolymer or copolymer comprising passing ethylene with or without at least one alpha-olefin comonomer having 3 or more carbon atoms into contact with a mixed catalyst system, under polymerization conditions, said mixed catalyst system comprising:n (a) the reaction product of (i) a vanadium halide having the formula VX₃ wherein X is chlorine, bromine, or iodine and each X is alike or different; (ii) a modifier having the formula BX₃ or AlR (3-a) X a wherein X as defined above; R is an alkyl radical having 1 to 14 carbon atoms; each R is alike or different; and a is 0, 1, or 2 and (iii) an electron donor, which is a liquid Lewis base in which the vanadium halide and modifier are soluble; (b) one of the following: n(i) a complex having the formula ZrMg b X c (ED) d wherein X as defined above; ED is an electron donor, which is a liquid Lewis base in which the precursors of the complex are soluble; b is a number from 1 to 3; c is a positive number equal to or less than 4+2b; and d is a number from 4 to 10; or n(ii) a vanadium oxy compound having the formula VOX₃, VOX₂, VOX, or VO₂X wherein X is as defined above, of VO(OR)₃ wherein R is a monovalent hydrocarbon radical having 2 to 10 carbon atoms and each R can be alike or different, n wherein the vanadium halide and the vanadium oxy compound are supported; (c) a hydrocarbyl aluminum cocatalyst; and (d) a halocarbon promoter having the formula R e CX (4-e) wherein R is hydrogen or an unsubstituted or halo substituted alkyl radical having 1 to 6 carbon atoms; each R is alike or different; X is chlorine, bromine, iodine, or fluorine; each X is alike or different; and e is 0, 1, or 2 provided that, if no fluorine is present, e is 2. |
isCitedBy | http://rdf.ncbi.nlm.nih.gov/pubchem/patent/EP-0724604-A4 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/EP-0692498-A1 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-5204304-A http://rdf.ncbi.nlm.nih.gov/pubchem/patent/TR-26714-A http://rdf.ncbi.nlm.nih.gov/pubchem/patent/EP-0464710-A3 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-5155079-A http://rdf.ncbi.nlm.nih.gov/pubchem/patent/EP-0464710-A2 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-5369194-A http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-5405817-A http://rdf.ncbi.nlm.nih.gov/pubchem/patent/WO-0224768-A1 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/SG-88707-A1 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-5399540-A http://rdf.ncbi.nlm.nih.gov/pubchem/patent/EP-0724604-A1 |
priorityDate | 1987-10-29-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 72.