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filingDate 1986-10-13-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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publicationDate 1987-05-13-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber EP-0221400-A1
titleOfInvention Cationic paper-sizing agents
abstract a) 7 bis 40 Gew.-% N,N-Dimethylaminoethylacrylat undoder -methacrylat, b) 40 bis 80 Gew.-% Styrol und c 1 4 bis 50 Gew.-% Acrvlnitril nauflöst, wobei die Summe der Komponenten a) bis c) stets 100 Gew.-% beträgt und von den Dimethylaminogruppen desTerpolymeren mindestens 10 % mit Monoepoxiden, mit Ausnahme von Epihalogenhydrinen, quaterniert und die restlichen protoniert sind, und indem man in Gegenwart von 10 bis 70 Gew.-% - bezogen auf das folgende Monomergemisch - dieses Emulgators d) 5 bis 95 Gew.-% Acrylnitril, Methacrylnitril oder Styrol bzw. deren Mischungen und e) 5 bis 95 Gew.-% Acrylsäure- und/oder Methacrylsäureester mit 1 bis 12 C-Atomen im Alkoholrest wobei die Summe der Komponenten d) und e) stets 100 Gew.-% beträgt - emulgiert und die so erhaltene Emulsion einer Radikalisch initierten Emulsionspolymerisation bei Temperaturen von 20 bis 150°C unterwirft. Cationic sizing agents for paper, obtainable in that a water-soluble cationic, chemically uniform terpolymer compound is formed in the aqueous medium a) 7 to 40% by weight of N, N-dimethylaminoethyl acrylate and or methacrylate, b) 40 to 80 wt .-% styrene and c 1 4 to 50 wt .-% acrylonitrile dissolves, wherein the sum of components a) to c) is always 100% by weight and at least 10% of the dimethylamino groups of the terpolymer are quaternized with monoepoxides, with the exception of epihalohydrins, and the rest are protonated, and in the presence of 10 to 70% by weight - based on the following monomer mixture - of this emulsifier d) 5 to 95 wt .-% acrylonitrile, methacrylonitrile or styrene or mixtures thereof and e) 5 to 95% by weight of acrylic acid and / or methacrylic acid esters with 1 to 12 carbon atoms in the alcohol radical, the sum of components d) and e) always being 100% by weight - emulsified and the resulting emulsion of a radical initiated emulsion polymerization at temperatures of 20 to 150 ° C.
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