http://rdf.ncbi.nlm.nih.gov/pubchem/patent/EP-0171248-A2

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filingDate 1985-07-29-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_d403eeee0d35f6f39d9c591e79191d14
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_4e37a5bb57c5b47d53878d7e31eed364
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publicationDate 1986-02-12-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber EP-0171248-A2
titleOfInvention Process for the preparation of 2,2,2-trifluoroethanol
abstract A continuous process is disclosed for preparing 2,2,2-trifluoroethanol from 2-halo-1,1,1-trifluoroethane, preferably 2-chloro-1,1,1-trifluoroethane. In the process, 2-halo-1,1,1-trifluoroethane, a carboxylic acid salt and a hydroxylated compound such as water are continuously provided to a reaction mixture in a reactor. The 2-halo-1,1,1-trifluoroethane, the carboxylic acid salt and the hydroxylated compound are reacted therein at a reaction pressure at or above the autogenously developed pressure and at a reaction temperature of from about 223°C to about the critical temperature of the hydroxylated compound. At least a portion of the reaction product mixture is continuously withdrawn from the reactor and unreacted 2-halo-1,1,1-trifluoroethane is separated therefrom. The separated unreacted 2-halo-1,1,1-trifluoroethanne is recycled as part of the 2-halo-1,1,1-trifluoroethane provided to the reaction mixture. The 2,2,2-trifluoroethanol is recovered from the reaction product mixture.
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