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filingDate 1983-04-21-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_7fdef62c61ad3c8dea9572f3847e6d65
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publicationDate 1983-11-02-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber EP-0093074-A2
titleOfInvention Regulation of the molecular weight of polybutadiene.
abstract There is disclosed a process for the regulation of the molecular weight of a high-cis 1,4-Polybutadiene prepared by polymerizing 1,3-butadiene in a solution of an aliphatic and/or cycloaliphatic or aromatic solvent system employing as a catalyst system a mixture of (1) an organonickel compound, (2) an organoaluminum compound, and (3) a fluorine containing compound selected from the group consisting of hydrogen fluoride and hydrogen fluoride complexes which are prepared by complexing hydrogen fluoride with a ketone, an aldehyde, a nitrile, a mineral acid containing oxygen, an ester, an ether, an alcohol, a phenol or water; said polymerization being conducted in the presence of small amounts of olefins selected from the group consisting of 1-butene, isobutylene, cis and trans-2-butene and allene.
priorityDate 1982-04-26-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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