http://rdf.ncbi.nlm.nih.gov/pubchem/patent/EP-0083190-A1
Outgoing Links
Predicate | Object |
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assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_d9cb217f83556ce2a418344c2d485415 |
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08F295-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08F136-06 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F136-06 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F295-00 |
filingDate | 1982-12-20-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_da52a49b8685fd4e320872e069b994b8 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_dc1dee6e0c1dd265b8536d36976889c0 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_1f4a7df9b2fb237166462b3e7a32eeab http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_77b0bf3c80af33ab1c5bb8c49aae16e6 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_b2a598db487f2ace753b9847778b9206 |
publicationDate | 1983-07-06-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | EP-0083190-A1 |
titleOfInvention | Process for producing polybutadiene rubber with enhanced mechanical strength |
abstract | A polybutadiene rubber having an enhanced mechanical strength is produced in such a manner that the contents of water and carbon disulfide in a solution of 1,3-butadiene and carbon disulfide in an inert organic solvent is controlled to 0.2 to 5 m moles and 20 m moles or less, respectively, per liter of the 1,3-butadiene-carbon disulfide solution; a first polymerization mixture is prepared from the controlled 1,3-butadiene-carbon disulfide solution, an organic aluminum compound of the formula Al R n X 3-n , wherein R = C 1-6 alkyl, phenyl or cycloalkyl, X = halogen, and n = 1.5-2.0, and a cobalt compound, for example, by aging a mixture of the controlled 1,3-butadiene-carbon disulfide solution with the aluminum compound for at least one minutes and then by admixing the aged mixture with the cobalt compound; the first polymerization mixture is subjected to a cis-1,4- polymerization; a second polymerization comprising the resultant cis-1,4-polybutadiene, non-reacted 1,3-butadiene, the inert organic solvent, an organic aluminum compound of the formula AIR3, a cobalt compound, and the carbon disulfide is subjected to a 1,2-polymerization to produce a polybutadiene rubber consisting essentially of ε% to 30% by weight of a boiling n-hexane-insoluble fraction and 70% to 95% by weight of a boiling n-hexane-soluble fraction thereof; and after the 1,2-polymerization is shortstopped, the resultant polybutadiene rubber is isolated from the 1,2- polymerization mixture. |
isCitedBy | http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-6765066-B2 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/WO-0149764-A1 |
priorityDate | 1981-12-24-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 120.